The name of the layers of the earth's atmosphere. Upper layers of the atmosphere. Composition of the Earth's atmosphere

The atmosphere is the gaseous shell of our planet, which rotates along with the Earth. The gas in the atmosphere is called air. The atmosphere is in contact with the hydrosphere and partially covers the lithosphere. But the upper limits are difficult to determine. It is conventionally accepted that the atmosphere extends upward for approximately three thousand kilometers. There it smoothly flows into airless space.

Chemical composition of the Earth's atmosphere

The formation of the chemical composition of the atmosphere began about four billion years ago. Initially, the atmosphere consisted only of light gases - helium and hydrogen. According to scientists, the initial prerequisites for the creation of a gas shell around the Earth were volcanic eruptions, which, along with lava, emitted huge amounts of gases. Subsequently, gas exchange began with water spaces, with living organisms, and with the products of their activities. The composition of the air gradually changed and was fixed in its modern form several million years ago.

The main components of the atmosphere are nitrogen (about 79%) and oxygen (20%). The remaining percentage (1%) is made up of the following gases: argon, neon, helium, methane, carbon dioxide, hydrogen, krypton, xenon, ozone, ammonia, sulfur and nitrogen dioxides, nitrous oxide and carbon monoxide, which are included in this one percent.

In addition, the air contains water vapor and particulate matter (pollen, dust, salt crystals, aerosol impurities).

Recently, scientists have noted not a qualitative, but a quantitative change in some air ingredients. And the reason for this is man and his activities. In the last 100 years alone, carbon dioxide levels have increased significantly! This is fraught with many problems, the most global of which is climate change.

Formation of weather and climate

The atmosphere plays a critical role in shaping the climate and weather on Earth. A lot depends on the amount of sunlight, the nature of the underlying surface and atmospheric circulation.

Let's look at the factors in order.

1. The atmosphere transmits the heat of the sun's rays and absorbs harmful radiation. The ancient Greeks knew that the rays of the Sun fall on different parts of the Earth at different angles. The word “climate” itself translated from ancient Greek means “slope”. So, at the equator, the sun's rays fall almost vertically, which is why it is very hot here. The closer to the poles, the greater the angle of inclination. And the temperature drops.

2. Due to the uneven heating of the Earth, air currents are formed in the atmosphere. They are classified according to their sizes. The smallest (tens and hundreds of meters) are local winds. This is followed by monsoons and trade winds, cyclones and anticyclones, and planetary frontal zones.

All these air masses are constantly moving. Some of them are quite static. For example, trade winds that blow from the subtropics towards the equator. The movement of others depends largely on atmospheric pressure.

3. Atmospheric pressure is another factor influencing climate formation. This is the air pressure on the surface of the earth. As is known, air masses move from an area with high atmospheric pressure towards an area where this pressure is lower.

A total of 7 zones are allocated. The equator is a low pressure zone. Further, on both sides of the equator up to the thirties latitudes there is an area of ​​high pressure. From 30° to 60° - low pressure again. And from 60° to the poles is a high pressure zone. Air masses circulate between these zones. Those that come from the sea to land bring rain and bad weather, and those that blow from the continents bring clear and dry weather. In places where air currents collide, atmospheric front zones are formed, which are characterized by precipitation and inclement, windy weather.

Scientists have proven that even a person’s well-being depends on atmospheric pressure. According to international standards, normal atmospheric pressure is 760 mm Hg. column at a temperature of 0°C. This indicator is calculated for those areas of land that are almost level with sea level. With altitude the pressure decreases. Therefore, for example, for St. Petersburg 760 mm Hg. - this is the norm. But for Moscow, which is located higher, normal pressure is 748 mm Hg.

The pressure changes not only vertically, but also horizontally. This is especially felt during the passage of cyclones.

The structure of the atmosphere

The atmosphere is reminiscent of a layer cake. And each layer has its own characteristics.

. Troposphere- the layer closest to the Earth. The "thickness" of this layer changes with distance from the equator. Above the equator, the layer extends upward by 16-18 km, in temperate zones by 10-12 km, at the poles by 8-10 km.

It is here that 80% of the total air mass and 90% of water vapor are contained. Clouds form here, cyclones and anticyclones arise. The air temperature depends on the altitude of the area. On average, it decreases by 0.65° C for every 100 meters.

. Tropopause- transition layer of the atmosphere. Its height ranges from several hundred meters to 1-2 km. The air temperature in summer is higher than in winter. For example, above the poles in winter it is -65° C. And above the equator it is -70° C at any time of the year.

. Stratosphere- this is a layer whose upper boundary lies at an altitude of 50-55 kilometers. Turbulence here is low, the content of water vapor in the air is negligible. But there is a lot of ozone. Its maximum concentration is at an altitude of 20-25 km. In the stratosphere, the air temperature begins to rise and reaches +0.8° C. This is due to the fact that the ozone layer interacts with ultraviolet radiation.

. Stratopause- a low intermediate layer between the stratosphere and the mesosphere that follows it.

. Mesosphere- the upper boundary of this layer is 80-85 kilometers. Complex photochemical processes involving free radicals occur here. They are the ones who provide that gentle blue glow of our planet, which is seen from space.

Most comets and meteorites burn up in the mesosphere.

. Mesopause- the next intermediate layer, the air temperature in which is at least -90°.

. Thermosphere- the lower boundary begins at an altitude of 80 - 90 km, and the upper boundary of the layer runs approximately at 800 km. The air temperature is rising. It can vary from +500° C to +1000° C. During the day, temperature fluctuations amount to hundreds of degrees! But the air here is so rarefied that understanding the term “temperature” as we imagine it is not appropriate here.

. Ionosphere- combines the mesosphere, mesopause and thermosphere. The air here consists mainly of oxygen and nitrogen molecules, as well as quasi-neutral plasma. The sun's rays entering the ionosphere strongly ionize air molecules. In the lower layer (up to 90 km) the degree of ionization is low. The higher, the greater the ionization. So, at an altitude of 100-110 km, electrons are concentrated. This helps to reflect short and medium radio waves.

The most important layer of the ionosphere is the upper one, which is located at an altitude of 150-400 km. Its peculiarity is that it reflects radio waves, and this facilitates the transmission of radio signals over considerable distances.

It is in the ionosphere that such a phenomenon as the aurora occurs.

. Exosphere- consists of oxygen, helium and hydrogen atoms. The gas in this layer is very rarefied and hydrogen atoms often escape into outer space. Therefore, this layer is called the “dispersion zone”.

The first scientist to suggest that our atmosphere has weight was the Italian E. Torricelli. Ostap Bender, for example, in his novel “The Golden Calf” lamented that every person is pressed by a column of air weighing 14 kg! But the great schemer was a little mistaken. An adult experiences pressure of 13-15 tons! But we do not feel this heaviness, because atmospheric pressure is balanced by the internal pressure of a person. The weight of our atmosphere is 5,300,000,000,000,000 tons. The figure is colossal, although it is only a millionth of the weight of our planet.

Earth's atmosphere

Atmosphere(from. Old Greekἀτμός - steam and σφαῖρα - ball) - gas shell ( geosphere), surrounding the planet Earth. Its inner surface covers hydrosphere and partially bark, the outer one borders on the near-Earth part of outer space.

The set of branches of physics and chemistry that study the atmosphere is usually called atmospheric physics. The atmosphere determines weather on the surface of the Earth, studying weather meteorology, and long-term variations climate - climatology.

The structure of the atmosphere

The structure of the atmosphere

Troposphere

Its upper limit is at an altitude of 8-10 km in polar, 10-12 km in temperate and 16-18 km in tropical latitudes; lower in winter than in summer. The lower, main layer of the atmosphere. Contains more than 80% of the total mass of atmospheric air and about 90% of all water vapor present in the atmosphere. In the troposphere are highly developed turbulence And convection, arise clouds, are developing cyclones And anticyclones. Temperature decreases with increasing altitude with average vertical gradient 0.65°/100 m

The following are accepted as “normal conditions” at the Earth’s surface: density 1.2 kg/m3, barometric pressure 101.35 kPa, temperature plus 20 °C and relative humidity 50%. These conditional indicators have purely engineering significance.

Stratosphere

A layer of the atmosphere located at an altitude of 11 to 50 km. Characterized by a slight change in temperature in the 11-25 km layer (lower layer of the stratosphere) and an increase in the 25-40 km layer from −56.5 to 0.8 ° WITH(upper layer of the stratosphere or region inversions). Having reached a value of about 273 K (almost 0 ° C) at an altitude of about 40 km, the temperature remains constant up to an altitude of about 55 km. This region of constant temperature is called stratopause and is the boundary between the stratosphere and mesosphere.

Stratopause

The boundary layer of the atmosphere between the stratosphere and mesosphere. In the vertical temperature distribution there is a maximum (about 0 °C).

Mesosphere

Earth's atmosphere

Mesosphere begins at an altitude of 50 km and extends to 80-90 km. Temperature decreases with height with an average vertical gradient of (0.25-0.3)°/100 m. The main energy process is radiant heat transfer. Complex photochemical processes involving free radicals, vibrationally excited molecules, etc., cause the glow of the atmosphere.

Mesopause

Transitional layer between the mesosphere and thermosphere. There is a minimum in the vertical temperature distribution (about -90 °C).

Karman Line

The height above sea level, which is conventionally accepted as the boundary between the Earth's atmosphere and space.

Thermosphere

Main article: Thermosphere

The upper limit is about 800 km. The temperature rises to altitudes of 200-300 km, where it reaches values ​​of the order of 1500 K, after which it remains almost constant to high altitudes. Under the influence of ultraviolet and x-ray solar radiation and cosmic radiation, air ionization occurs (“ auroras") - main areas ionosphere lie inside the thermosphere. At altitudes above 300 km, atomic oxygen predominates.

Atmospheric layers up to an altitude of 120 km

Exosphere (scattering sphere)

Exosphere- dispersion zone, the outer part of the thermosphere, located above 700 km. The gas in the exosphere is very rarefied, and from here its particles leak into interplanetary space ( dissipation).

Up to an altitude of 100 km, the atmosphere is a homogeneous, well-mixed mixture of gases. In higher layers, the distribution of gases by height depends on their molecular weights; the concentration of heavier gases decreases faster with distance from the Earth's surface. Due to the decrease in gas density, the temperature drops from 0 °C in the stratosphere to −110 °C in the mesosphere. However, the kinetic energy of individual particles at altitudes of 200-250 km corresponds to a temperature of ~1500 °C. Above 200 km, significant fluctuations in temperature and gas density in time and space are observed.

At an altitude of about 2000-3000 km, the exosphere gradually turns into the so-called near space vacuum, which is filled with highly rarefied particles of interplanetary gas, mainly hydrogen atoms. But this gas represents only part of the interplanetary matter. The other part consists of dust particles of cometary and meteoric origin. In addition to extremely rarefied dust particles, electromagnetic and corpuscular radiation of solar and galactic origin penetrates into this space.

The troposphere accounts for about 80% of the mass of the atmosphere, the stratosphere - about 20%; the mass of the mesosphere is no more than 0.3%, the thermosphere is less than 0.05% of the total mass of the atmosphere. Based on the electrical properties in the atmosphere, the neutronosphere and ionosphere are distinguished. It is currently believed that the atmosphere extends to an altitude of 2000-3000 km.

Depending on the composition of the gas in the atmosphere, they emit homosphere And heterosphere. Heterosphere - This is the area where gravity affects the separation of gases, since their mixing at such an altitude is negligible. This implies a variable composition of the heterosphere. Below it lies a well-mixed, homogeneous part of the atmosphere, called homosphere. The boundary between these layers is called turbo pause, it lies at an altitude of about 120 km.

Physical properties

The thickness of the atmosphere is approximately 2000 - 3000 km from the Earth's surface. Total mass air- (5.1-5.3)×10 18 kg. Molar mass clean dry air is 28.966. Pressure at 0 °C at sea level 101.325 kPa; critical temperature?140.7 °C; critical pressure 3.7 MPa; C p 1.0048×10 3 J/(kg K) (at 0 °C), C v 0.7159×10 3 J/(kg K) (at 0 °C). The solubility of air in water at 0 °C is 0.036%, at 25 °C - 0.22%.

Physiological and other properties of the atmosphere

Already at an altitude of 5 km above sea level, an untrained person develops oxygen starvation and without adaptation, a person’s performance is significantly reduced. The physiological zone of the atmosphere ends here. Human breathing becomes impossible at an altitude of 15 km, although up to approximately 115 km the atmosphere contains oxygen.

The atmosphere supplies us with the oxygen necessary for breathing. However, due to the drop in the total pressure of the atmosphere, as you rise to altitude, the partial pressure of oxygen decreases accordingly.

The human lungs constantly contain about 3 liters of alveolar air. Partial pressure oxygen in alveolar air at normal atmospheric pressure is 110 mm Hg. Art., carbon dioxide pressure - 40 mm Hg. Art., and water vapor - 47 mm Hg. Art. With increasing altitude, oxygen pressure drops, and the total vapor pressure of water and carbon dioxide in the lungs remains almost constant - about 87 mm Hg. Art. The supply of oxygen to the lungs will completely stop when the ambient air pressure becomes equal to this value.

At an altitude of about 19-20 km, the atmospheric pressure drops to 47 mm Hg. Art. Therefore, at this altitude, water and interstitial fluid begin to boil in the human body. Outside the pressurized cabin at these altitudes, death occurs almost instantly. Thus, from the point of view of human physiology, “space” begins already at an altitude of 15-19 km.

Dense layers of air - the troposphere and stratosphere - protect us from the damaging effects of radiation. With sufficient rarefaction of air, at altitudes of more than 36 km, ionizing agents have an intense effect on the body. radiation- primary cosmic rays; At altitudes of more than 40 km, the ultraviolet part of the solar spectrum is dangerous for humans.

As we rise to an ever greater height above the Earth's surface, such familiar phenomena observed in the lower layers of the atmosphere as the propagation of sound, the emergence of aerodynamic lift and resistance, heat transfer convection and etc.

In rarefied layers of air, distribution sound turns out to be impossible. Up to altitudes of 60-90 km, it is still possible to use air resistance and lift for controlled aerodynamic flight. But starting from altitudes of 100-130 km, concepts familiar to every pilot numbers M And sound barrier lose their meaning, there is a conditional Karman Line beyond which begins the sphere of purely ballistic flight, which can only be controlled using reactive forces.

At altitudes above 100 km, the atmosphere is deprived of another remarkable property - the ability to absorb, conduct and transmit thermal energy by convection (i.e. by mixing air). This means that various elements of equipment on the orbital space station will not be able to be cooled from the outside in the same way as is usually done on an airplane - with the help of air jets and air radiators. At such a height, as in space generally, the only way to transfer heat is thermal radiation.

Atmospheric composition

Composition of dry air

The Earth's atmosphere consists mainly of gases and various impurities (dust, water droplets, ice crystals, sea salts, combustion products).

The concentration of gases that make up the atmosphere is almost constant, with the exception of water (H 2 O) and carbon dioxide (CO 2).

In addition to the gases indicated in the table, the atmosphere contains SO 2, NH 3, CO, ozone, hydrocarbons, HCl, HF, couples Hg, I 2 , and also NO and many other gases in small quantities. The troposphere constantly contains a large number of suspended solid and liquid particles ( aerosol).

History of atmospheric formation

According to the most common theory, the Earth's atmosphere has had four different compositions over time. Initially it consisted of light gases ( hydrogen And helium), captured from interplanetary space. This is the so-called primary atmosphere(about four billion years ago). At the next stage, active volcanic activity led to the saturation of the atmosphere with gases other than hydrogen (carbon dioxide, ammonia, water vapor). This is how it was formed secondary atmosphere(about three billion years before the present day). This atmosphere was restorative. Further, the process of atmosphere formation was determined by the following factors:

leakage of light gases (hydrogen and helium) into interplanetary space;

chemical reactions occurring in the atmosphere under the influence of ultraviolet radiation, lightning discharges and some other factors.

Gradually these factors led to the formation tertiary atmosphere, characterized by a much lower content of hydrogen and a much higher content of nitrogen and carbon dioxide (formed as a result of chemical reactions from ammonia and hydrocarbons).

Nitrogen

The formation of a large amount of N 2 is due to the oxidation of the ammonia-hydrogen atmosphere by molecular O 2, which began to come from the surface of the planet as a result of photosynthesis, starting 3 billion years ago. N2 is also released into the atmosphere as a result of denitrification of nitrates and other nitrogen-containing compounds. Nitrogen is oxidized by ozone to NO in the upper atmosphere.

Nitrogen N 2 reacts only under specific conditions (for example, during a lightning discharge). The oxidation of molecular nitrogen by ozone during electrical discharges is used in the industrial production of nitrogen fertilizers. They can oxidize it with low energy consumption and convert it into a biologically active form. cyanobacteria (blue-green algae) and nodule bacteria that form rhizobial symbiosis With legumes plants, so-called green manure.

Oxygen

The composition of the atmosphere began to change radically with the appearance on Earth living organisms, as a result photosynthesis accompanied by the release of oxygen and absorption of carbon dioxide. Initially, oxygen was spent on the oxidation of reduced compounds - ammonia, hydrocarbons, nitrous form gland contained in the oceans, etc. At the end of this stage, the oxygen content in the atmosphere began to increase. Gradually, a modern atmosphere with oxidizing properties formed. Since this caused serious and abrupt changes in many processes occurring in atmosphere, lithosphere And biosphere, this event was called Oxygen disaster.

During Phanerozoic the composition of the atmosphere and oxygen content underwent changes. They correlated primarily with the rate of deposition of organic sediment. Thus, during periods of coal accumulation, the oxygen content in the atmosphere apparently significantly exceeded the modern level.

Carbon dioxide

The content of CO 2 in the atmosphere depends on volcanic activity and chemical processes in the earth's shells, but most of all - on the intensity of biosynthesis and decomposition of organic matter in biosphere Earth. Almost the entire current biomass of the planet (about 2.4 × 10 12 tons ) is formed due to carbon dioxide, nitrogen and water vapor contained in the atmospheric air. Buried in ocean, V swamps and in forests organic matter turns into coal, oil And natural gas. (cm. Geochemical carbon cycle)

Noble gases

Source of inert gases - argon, helium And krypton- volcanic eruptions and decay of radioactive elements. The Earth in general and the atmosphere in particular are depleted of inert gases compared to space. It is believed that the reason for this lies in the continuous leakage of gases into interplanetary space.

Air pollution

Recently, the evolution of the atmosphere has begun to be influenced by Human. The result of his activities was a constant significant increase in the content of carbon dioxide in the atmosphere due to the combustion of hydrocarbon fuels accumulated in previous geological eras. Huge amounts of CO 2 are consumed during photosynthesis and absorbed by the world's oceans. This gas enters the atmosphere due to the decomposition of carbonate rocks and organic substances of plant and animal origin, as well as due to volcanism and human industrial activity. Over the past 100 years, the content of CO 2 in the atmosphere has increased by 10%, with the bulk (360 billion tons) coming from fuel combustion. If the growth rate of fuel combustion continues, then in the next 50 - 60 years the amount of CO 2 in the atmosphere will double and could lead to global climate change.

Fuel combustion is the main source of polluting gases ( CO, NO, SO 2 ). Sulfur dioxide is oxidized by atmospheric oxygen to SO 3 in the upper layers of the atmosphere, which in turn interacts with water and ammonia vapor, and the resulting sulfuric acid (H 2 SO 4 ) And ammonium sulfate ((NH 4 ) 2 SO 4 ) return to the surface of the Earth in the form of the so-called. acid rain. Usage internal combustion engines leads to significant atmospheric pollution with nitrogen oxides, hydrocarbons and lead compounds ( tetraethyl lead Pb(CH 3 CH 2 ) 4 ) ).

Aerosol pollution of the atmosphere is caused by both natural causes (volcanic eruptions, dust storms, entrainment of drops of sea water and plant pollen, etc.) and human economic activities (mining ores and building materials, burning fuel, making cement, etc.). Intense large-scale release of particulate matter into the atmosphere is one of the possible causes of climate change on the planet.

The atmosphere has a layered structure. The boundaries between layers are not sharp and their height depends on latitude and time of year. The layered structure is the result of temperature changes at different altitudes. Weather is formed in the troposphere (lower about 10 km: about 6 km above the poles and more than 16 km above the equator). And the upper boundary of the troposophere is higher in summer than in winter.

From the surface of the Earth upward these layers are:

Troposphere

Stratosphere

Mesosphere

Thermosphere

Exosphere

Troposphere

The lower part of the atmosphere, up to a height of 10-15 km, in which 4/5 of the total mass of atmospheric air is concentrated, is called the troposphere. It is characteristic that the temperature here drops with height by an average of 0.6°/100 m (in some cases, the vertical temperature distribution varies widely). The troposphere contains almost all of the atmospheric water vapor and produces almost all of the clouds. Turbulence is also highly developed here, especially near the earth's surface, as well as in the so-called jet streams in the upper part of the troposphere.

The height to which the troposphere extends over each location on Earth varies from day to day. In addition, even on average it varies at different latitudes and in different seasons of the year. On average, the annual troposphere extends over the poles to a height of about 9 km, over temperate latitudes up to 10-12 km and above the equator up to 15-17 km. The average annual air temperature at the earth's surface is about +26° at the equator and about -23° at the north pole. At the upper boundary of the troposphere above the equator, the average temperature is about -70°, above the North Pole in winter about -65°, and in summer about -45°.

The air pressure at the upper boundary of the troposphere, corresponding to its height, is 5-8 times less than at the earth's surface. Consequently, the bulk of atmospheric air is located in the troposphere. The processes occurring in the troposphere are directly and decisively important for the weather and climate at the earth's surface.

All water vapor is concentrated in the troposphere and that is why all clouds form within the troposphere. Temperature decreases with altitude.

The sun's rays easily pass through the troposphere, and the heat that radiates from the Earth, heated by the sun's rays, accumulates in the troposphere: gases such as carbon dioxide, methane and water vapor retain heat. This mechanism of warming the atmosphere from the Earth, heated by solar radiation, is called the greenhouse effect. Precisely because the source of heat for the atmosphere is the Earth, the air temperature decreases with height

The boundary between the turbulent troposphere and the calm stratosphere is called the tropopause. This is where fast-moving winds called "jet streams" form.

It was once assumed that the temperature of the atmosphere falls above the troposophere, but measurements in the high layers of the atmosphere have shown that this is not so: immediately above the tropopause the temperature is almost constant, and then begins to increase. Strong horizontal winds blow in the stratosphere without forming turbulence. The air in the stratosphere is very dry and therefore clouds are rare. So-called nacreous clouds are formed.

The stratosphere is very important for life on Earth, as it is in this layer that there is a small amount of ozone, which absorbs strong ultraviolet radiation that is harmful to life. By absorbing ultraviolet radiation, ozone heats the stratosphere.

Stratosphere

Above the troposphere to an altitude of 50-55 km lies the stratosphere, characterized by the fact that the temperature in it, on average, increases with height. The transition layer between the troposphere and stratosphere (1-2 km thick) is called the tropopause.

Above were data on the temperature at the upper boundary of the troposphere. These temperatures are also typical for the lower stratosphere. Thus, the air temperature in the lower stratosphere above the equator is always very low; Moreover, in summer it is much lower than above the pole.

The lower stratosphere is more or less isothermal. But, starting from an altitude of about 25 km, the temperature in the stratosphere quickly increases with altitude, reaching maximum positive values ​​at an altitude of about 50 km (from +10 to +30°). Due to the increase in temperature with altitude, turbulence in the stratosphere is low.

There is negligible water vapor in the stratosphere. However, at altitudes of 20-25 km, very thin, so-called nacreous clouds are sometimes observed in high latitudes. During the day they are not visible, but at night they appear to glow, as they are illuminated by the sun below the horizon. These clouds are made up of supercooled water droplets. The stratosphere is also characterized by the fact that it mainly contains atmospheric ozone, as mentioned above

Mesosphere

Above the stratosphere lies the mesosphere layer, up to approximately 80 km. Here the temperature drops with altitude to several tens of degrees below zero. Due to the rapid drop in temperature with height, turbulence is highly developed in the mesosphere. At altitudes close to the upper boundary of the mesosphere (75-90 km), another special kind of clouds are observed, also illuminated by the sun at night, the so-called noctilucent ones. They are most likely composed of ice crystals.

At the upper boundary of the mesosphere, air pressure is 200 times less than at the earth's surface. Thus, in the troposphere, stratosphere and mesosphere together, up to an altitude of 80 km, lies more than 99.5% of the total mass of the atmosphere. The overlying layers account for a negligible amount of air

At an altitude of about 50 km above the Earth, the temperature begins to fall again, marking the upper limit of the stratosphere and the beginning of the next layer, the mesosphere. The mesosphere has the coldest temperature in the atmosphere: from -2 to -138 degrees Celsius. The highest clouds are also located here: in clear weather they can be seen at sunset. They are called noctilucent (glowing at night).

Thermosphere

The upper part of the atmosphere, above the mesosphere, is characterized by very high temperatures and is therefore called the thermosphere. However, two parts are distinguished in it: the ionosphere, extending from the mesosphere to altitudes of the order of a thousand kilometers, and the outer part lying above it - the exosphere, which turns into the earth's corona.

The air in the ionosphere is extremely rarefied. We have already indicated that at altitudes of 300-750 km its average density is about 10-8-10-10 g/m3. But even with such a low density, each cubic centimeter of air at an altitude of 300 km still contains about one billion (109) molecules or atoms, and at an altitude of 600 km - over 10 million (107). This is several orders of magnitude greater than the content of gases in interplanetary space.

The ionosphere, as the name itself says, is characterized by a very strong degree of ionization of the air - the ion content here is many times greater than in the underlying layers, despite the strong general rarefaction of the air. These ions are mainly charged oxygen atoms, charged nitric oxide molecules, and free electrons. Their content at altitudes of 100-400 km is about 1015-106 per cubic centimeter.

Several layers, or regions, with maximum ionization are distinguished in the ionosphere, especially at altitudes of 100-120 km and 200-400 km. But even in the spaces between these layers, the degree of ionization of the atmosphere remains very high. The position of the ionospheric layers and the concentration of ions in them change all the time. Sporadic collections of electrons with particularly high concentrations are called electron clouds.

The electrical conductivity of the atmosphere depends on the degree of ionization. Therefore, in the ionosphere, the electrical conductivity of air is generally 1012 times greater than that of the earth’s surface. Radio waves experience absorption, refraction and reflection in the ionosphere. Waves with a length of more than 20 m cannot pass through the ionosphere at all: they are reflected by electron layers of low concentration in the lower part of the ionosphere (at altitudes of 70-80 km). Medium and short waves are reflected by the overlying ionospheric layers.

It is due to reflection from the ionosphere that long-distance communication on short waves is possible. Multiple reflections from the ionosphere and the earth's surface allow short waves to travel in a zigzag manner over long distances, bending around the surface of the globe. Since the position and concentration of ionospheric layers are constantly changing, the conditions for absorption, reflection and propagation of radio waves also change. Therefore, for reliable radio communications, continuous study of the state of the ionosphere is necessary. Observations of the propagation of radio waves are precisely the means for such research.

In the ionosphere, auroras and the glow of the night sky, which is close in nature to them in nature, are observed - constant luminescence of atmospheric air, as well as sharp fluctuations in the magnetic field - ionospheric magnetic storms.

Ionization in the ionosphere owes its existence to the action of ultraviolet radiation from the Sun. Its absorption by molecules of atmospheric gases leads to the formation of charged atoms and free electrons, as discussed above. Magnetic field fluctuations in the ionosphere and auroras depend on fluctuations in solar activity. Changes in solar activity are associated with changes in the flow of corpuscular radiation coming from the Sun into the earth's atmosphere. Namely, corpuscular radiation is of primary importance for these ionospheric phenomena.

The temperature in the ionosphere increases with altitude to very high values. At altitudes of about 800 km it reaches 1000°.

When we talk about high temperatures in the ionosphere, we mean that particles of atmospheric gases move there at very high speeds. However, the air density in the ionosphere is so low that a body located in the ionosphere, for example a flying satellite, will not be heated by heat exchange with the air. The temperature regime of the satellite will depend on its direct absorption of solar radiation and on the release of its own radiation into the surrounding space. The thermosphere is located above the mesosphere at an altitude of 90 to 500 km above the Earth's surface. Gas molecules here are highly scattered and absorb X-rays and short-wavelength ultraviolet radiation. Because of this, temperatures can reach 1000 degrees Celsius.

The thermosphere basically corresponds to the ionosphere, where ionized gas reflects radio waves back to Earth, a phenomenon that makes radio communications possible.

Exosphere

Above 800-1000 km, the atmosphere passes into the exosphere and gradually into interplanetary space. The speeds of movement of gas particles, especially light ones, are very high here, and due to the extreme rarefaction of the air at these altitudes, the particles can fly around the Earth in elliptical orbits without colliding with each other. Individual particles can have speeds sufficient to overcome gravity. For uncharged particles, the critical speed will be 11.2 km/sec. Such especially fast particles can, moving along hyperbolic trajectories, fly out of the atmosphere into outer space, “escape”, and dissipate. Therefore, the exosphere is also called the scattering sphere.

Mostly hydrogen atoms, which are the dominant gas in the highest layers of the exosphere, escape.

Recently it was assumed that the exosphere, and with it the Earth’s atmosphere in general, ends at altitudes of about 2000-3000 km. But from observations by rockets and satellites, it appears that hydrogen escaping from the exosphere forms what is called the Earth's corona around the Earth, extending to more than 20,000 km. Of course, the density of gas in the earth's corona is negligible. For every cubic centimeter there are on average only about a thousand particles. But in interplanetary space the concentration of particles (mainly protons and electrons) is at least ten times less.

With the help of satellites and geophysical rockets, the existence in the upper part of the atmosphere and in near-Earth space of the Earth's radiation belt, starting at an altitude of several hundred kilometers and extending tens of thousands of kilometers from the earth's surface, has been established. This belt consists of electrically charged particles - protons and electrons, captured by the Earth's magnetic field and moving at very high speeds. Their energy is on the order of hundreds of thousands of electron volts. The radiation belt constantly loses particles in the earth's atmosphere and is replenished by flows of solar corpuscular radiation.

atmosphere temperature stratosphere troposphere

The gaseous envelope surrounding our planet Earth, known as the atmosphere, consists of five main layers. These layers originate on the surface of the planet, from sea level (sometimes below) and rise to outer space in the following sequence:

• Troposphere;
• Stratosphere;
• Mesosphere;
• Thermosphere;
• Exosphere.

Diagram of the main layers of the Earth's atmosphere

In between each of these main five layers are transition zones called "pauses" where changes in air temperature, composition and density occur. Together with pauses, the Earth's atmosphere includes a total of 9 layers.

Troposphere: where weather occurs

Of all the layers of the atmosphere, the troposphere is the one with which we are most familiar (whether you realize it or not), since we live on its bottom - the surface of the planet. It envelops the surface of the Earth and extends upward for several kilometers. The word troposphere means "change of the globe." A very appropriate name, since this layer is where our everyday weather occurs.

Starting from the surface of the planet, the troposphere rises to a height of 6 to 20 km. The lower third of the layer, closest to us, contains 50% of all atmospheric gases. This is the only part of the entire atmosphere that breathes. Due to the fact that the air is heated from below by the earth's surface, which absorbs the thermal energy of the Sun, the temperature and pressure of the troposphere decrease with increasing altitude.

At the top there is a thin layer called the tropopause, which is just a buffer between the troposphere and the stratosphere.

Stratosphere: home of the ozone

The stratosphere is the next layer of the atmosphere. It extends from 6-20 km to 50 km above the Earth's surface. This is the layer in which most commercial airliners fly and hot air balloons travel.

Here the air does not flow up and down, but moves parallel to the surface in very fast air currents. As you rise, the temperature increases, thanks to the abundance of naturally occurring ozone (O3), a byproduct of solar radiation and oxygen, which has the ability to absorb the sun's harmful ultraviolet rays (any increase in temperature with altitude in meteorology is known as an "inversion") .

Because the stratosphere has warmer temperatures at the bottom and cooler temperatures at the top, convection (vertical movement of air masses) is rare in this part of the atmosphere. In fact, you can view a storm raging in the troposphere from the stratosphere because the layer acts as a convection cap that prevents storm clouds from penetrating.

After the stratosphere there is again a buffer layer, this time called the stratopause.

Mesosphere: middle atmosphere

The mesosphere is located approximately 50-80 km from the Earth's surface. The upper mesosphere is the coldest natural place on Earth, where temperatures can drop below -143°C.

Thermosphere: upper atmosphere

After the mesosphere and mesopause comes the thermosphere, located between 80 and 700 km above the surface of the planet, and contains less than 0.01% of the total air in the atmospheric envelope. Temperatures here reach up to +2000° C, but due to the extreme thinness of the air and the lack of gas molecules to transfer heat, these high temperatures are perceived as very cold.

Exosphere: the boundary between the atmosphere and space

At an altitude of about 700-10,000 km above the earth's surface is the exosphere - the outer edge of the atmosphere, bordering space. Here weather satellites orbit the Earth.

What about the ionosphere?

The ionosphere is not a separate layer, but in fact the term is used to refer to the atmosphere between 60 and 1000 km altitude. It includes the uppermost parts of the mesosphere, the entire thermosphere and part of the exosphere. The ionosphere gets its name because in this part of the atmosphere the radiation from the Sun is ionized when it passes through the Earth's magnetic fields at and. This phenomenon is observed from the ground as the northern lights.

The thickness of the atmosphere is approximately 120 km from the Earth's surface. The total mass of air in the atmosphere is (5.1-5.3) 10 18 kg. Of these, the mass of dry air is 5.1352 ±0.0003 10 18 kg, the total mass of water vapor is on average 1.27 10 16 kg.

Tropopause

The transition layer from the troposphere to the stratosphere, a layer of the atmosphere in which the decrease in temperature with height stops.

Stratosphere

A layer of the atmosphere located at an altitude of 11 to 50 km. Characterized by a slight change in temperature in the 11-25 km layer (lower layer of the stratosphere) and an increase in temperature in the 25-40 km layer from −56.5 to 0.8 ° (upper layer of the stratosphere or inversion region). Having reached a value of about 273 K (almost 0 °C) at an altitude of about 40 km, the temperature remains constant up to an altitude of about 55 km. This region of constant temperature is called the stratopause and is the boundary between the stratosphere and mesosphere.

Stratopause

The boundary layer of the atmosphere between the stratosphere and mesosphere. In the vertical temperature distribution there is a maximum (about 0 °C).

Mesosphere

Earth's atmosphere

Boundary of the Earth's atmosphere

Thermosphere

The upper limit is about 800 km. The temperature rises to altitudes of 200-300 km, where it reaches values ​​of the order of 1500 K, after which it remains almost constant to high altitudes. Under the influence of ultraviolet and x-ray solar radiation and cosmic radiation, ionization of the air (“ auroras”) occurs - the main regions of the ionosphere lie inside the thermosphere. At altitudes above 300 km, atomic oxygen predominates. The upper limit of the thermosphere is largely determined by the current activity of the Sun. During periods of low activity - for example, in 2008-2009 - there is a noticeable decrease in the size of this layer.

Thermopause

The region of the atmosphere adjacent to the thermosphere. In this region, the absorption of solar radiation is negligible and the temperature does not actually change with altitude.

Exosphere (scattering sphere)

Up to an altitude of 100 km, the atmosphere is a homogeneous, well-mixed mixture of gases. In higher layers, the distribution of gases by height depends on their molecular weights; the concentration of heavier gases decreases faster with distance from the Earth's surface. Due to the decrease in gas density, the temperature drops from 0 °C in the stratosphere to −110 °C in the mesosphere. However, the kinetic energy of individual particles at altitudes of 200-250 km corresponds to a temperature of ~150 °C. Above 200 km, significant fluctuations in temperature and gas density in time and space are observed.

At an altitude of about 2000-3500 km, the exosphere gradually turns into the so-called near space vacuum, which is filled with highly rarefied particles of interplanetary gas, mainly hydrogen atoms. But this gas represents only part of the interplanetary matter. The other part consists of dust particles of cometary and meteoric origin. In addition to extremely rarefied dust particles, electromagnetic and corpuscular radiation of solar and galactic origin penetrates into this space.

The troposphere accounts for about 80% of the mass of the atmosphere, the stratosphere - about 20%; the mass of the mesosphere is no more than 0.3%, the thermosphere is less than 0.05% of the total mass of the atmosphere. Based on the electrical properties in the atmosphere, the neutronosphere and ionosphere are distinguished. It is currently believed that the atmosphere extends to an altitude of 2000-3000 km.

Depending on the composition of the gas in the atmosphere, they emit homosphere And heterosphere. Heterosphere- This is the area where gravity affects the separation of gases, since their mixing at such an altitude is negligible. This implies a variable composition of the heterosphere. Below it lies a well-mixed, homogeneous part of the atmosphere, called the homosphere. The boundary between these layers is called the turbopause, it lies at an altitude of about 120 km.

Physiological and other properties of the atmosphere

Already at an altitude of 5 km above sea level, an untrained person begins to experience oxygen starvation and without adaptation, a person’s performance is significantly reduced. The physiological zone of the atmosphere ends here. Human breathing becomes impossible at an altitude of 9 km, although up to approximately 115 km the atmosphere contains oxygen.

The atmosphere supplies us with the oxygen necessary for breathing. However, due to the drop in the total pressure of the atmosphere, as you rise to altitude, the partial pressure of oxygen decreases accordingly.

In rarefied layers of air, sound propagation is impossible. Up to altitudes of 60-90 km, it is still possible to use air resistance and lift for controlled aerodynamic flight. But starting from altitudes of 100-130 km, the concepts of the M number and the sound barrier, familiar to every pilot, lose their meaning: there passes the conventional Karman line, beyond which the region of purely ballistic flight begins, which can only be controlled using reactive forces.

At altitudes above 100 km, the atmosphere is deprived of another remarkable property - the ability to absorb, conduct and transmit thermal energy by convection (i.e. by mixing air). This means that various elements of equipment on the orbital space station will not be able to be cooled from the outside in the same way as is usually done on an airplane - with the help of air jets and air radiators. At this altitude, as in space generally, the only way to transfer heat is thermal radiation.

History of atmospheric formation

According to the most common theory, the Earth's atmosphere has had three different compositions over time. Initially, it consisted of light gases (hydrogen and helium) captured from interplanetary space. This is the so-called primary atmosphere(about four billion years ago). At the next stage, active volcanic activity led to the saturation of the atmosphere with gases other than hydrogen (carbon dioxide, ammonia, water vapor). This is how it was formed secondary atmosphere(about three billion years before the present day). This atmosphere was restorative. Further, the process of atmosphere formation was determined by the following factors:

• leakage of light gases (hydrogen and helium) into interplanetary space;
• chemical reactions occurring in the atmosphere under the influence of ultraviolet radiation, lightning discharges and some other factors.

Gradually these factors led to the formation tertiary atmosphere, characterized by a much lower content of hydrogen and a much higher content of nitrogen and carbon dioxide (formed as a result of chemical reactions from ammonia and hydrocarbons).

Nitrogen

The formation of a large amount of nitrogen N2 is due to the oxidation of the ammonia-hydrogen atmosphere by molecular oxygen O2, which began to come from the surface of the planet as a result of photosynthesis, starting 3 billion years ago. Nitrogen N2 is also released into the atmosphere as a result of denitrification of nitrates and other nitrogen-containing compounds. Nitrogen is oxidized by ozone to NO in the upper atmosphere.

Nitrogen N 2 reacts only under specific conditions (for example, during a lightning discharge). The oxidation of molecular nitrogen by ozone during electrical discharges is used in small quantities in the industrial production of nitrogen fertilizers. Cyanobacteria (blue-green algae) and nodule bacteria that form rhizobial symbiosis with leguminous plants, the so-called, can oxidize it with low energy consumption and convert it into a biologically active form. green manure.

Oxygen

The composition of the atmosphere began to change radically with the appearance of living organisms on Earth, as a result of photosynthesis, accompanied by the release of oxygen and the absorption of carbon dioxide. Initially, oxygen was spent on the oxidation of reduced compounds - ammonia, hydrocarbons, ferrous form of iron contained in the oceans, etc. At the end of this stage, the oxygen content in the atmosphere began to increase. Gradually, a modern atmosphere with oxidizing properties formed. Since this caused serious and abrupt changes in many processes occurring in the atmosphere, lithosphere and biosphere, this event was called the Oxygen Catastrophe.

Noble gases

Air pollution

Recently, humans have begun to influence the evolution of the atmosphere. The result of his activities was a constant significant increase in the content of carbon dioxide in the atmosphere due to the combustion of hydrocarbon fuels accumulated in previous geological eras. Huge amounts of CO 2 are consumed during photosynthesis and absorbed by the world's oceans. This gas enters the atmosphere due to the decomposition of carbonate rocks and organic substances of plant and animal origin, as well as due to volcanism and human industrial activity. Over the past 100 years, the content of CO 2 in the atmosphere has increased by 10%, with the bulk (360 billion tons) coming from fuel combustion. If the growth rate of fuel combustion continues, then in the next 200-300 years the amount of CO 2 in the atmosphere will double and could lead to global climate change.

Fuel combustion is the main source of polluting gases (CO, SO2). Sulfur dioxide is oxidized by atmospheric oxygen to SO 3 in the upper layers of the atmosphere, which in turn interacts with water and ammonia vapor, and the resulting sulfuric acid (H 2 SO 4) and ammonium sulfate ((NH 4) 2 SO 4) are returned to the surface of the Earth in the form of the so-called. acid rain. The use of internal combustion engines leads to significant atmospheric pollution with nitrogen oxides, hydrocarbons and lead compounds (tetraethyl lead Pb(CH 3 CH 2) 4)).

Aerosol pollution of the atmosphere is caused by both natural causes (volcanic eruptions, dust storms, entrainment of drops of sea water and plant pollen, etc.) and human economic activities (mining ores and building materials, burning fuel, making cement, etc.). Intense large-scale release of particulate matter into the atmosphere is one of the possible causes of climate change on the planet.

see also

• Jacchia (atmosphere model)

Notes

Links

Literature

1. V. V. Parin, F. P. Kosmolinsky, B. A. Dushkov“Space biology and medicine” (2nd edition, revised and expanded), M.: “Prosveshcheniye”, 1975, 223 pp.
2. N. V. Gusakova“Environmental Chemistry”, Rostov-on-Don: Phoenix, 2004, 192 with ISBN 5-222-05386-5
3. Sokolov V. A. Geochemistry of natural gases, M., 1971;
4. McEwen M., Phillips L. Atmospheric Chemistry, M., 1978;
5. Wark K., Warner S. Air pollution. Sources and control, trans. from English, M.. 1980;
6. Monitoring of background pollution of natural environments. V. 1, L., 1982.